Two novel supramolecular isomers based on 2,2′-biimidazole derivative and zinc ions: Syntheses,structures and luminescent properties |
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Authors: | Yan-Hong Xu Ya-Qian Lan Ya-Hui Zhao Dong-Ying Du Guang-Juan Xu Kui-Zhan Shao Zhong-Min Su Yi Liao |
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Affiliation: | Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024, China |
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Abstract: | Two Zn(II)-2,2′-biimidazole derivative supramolecular isomers 1 and 2 formulated as Zn(L)] · 2H2O (H2L = 4,4′-(1H,1′H-2,2′-biimidazole-1,1′-diylbis(methylene))dibenzoic acid) have been synthesized, and structurally characterized by elemental analysis, IR spectroscopy, single-crystal X-ray crystallography. Complex 1 exhibits a 2D four-connected network with (43.63) topology when the zinc center and the L2? ligand act as four-connected nodes (or a distorted (4,4) grid if the Zn2(imidazole)4] units are considered as four-connected nodes). Complex 2 shows a novel four-connected twofold interpenetrated net with (42.62.82) topology when the zinc center and the L2? ligand act as four-connected nodes (or a twofold interpenetrated α-Po topology when Zn2(imidazole)4] units are identified as six-connected nodes). Moreover, complexes 1 and 2 both exhibit strong luminescent properties at room temperature. |
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