Nafion-H catalyzed condensation of acetophenone derivatives. A preparative route of 1,3,5-Triarylbenzenes [1] |
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Authors: | Takehiko Yamato Chieko Hideshima Masashi Tashiro G. K. Surya Prakash George A. Olah |
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Affiliation: | (1) Department of Industrial Chemistry, Faculty of Science and Engineering, Saga University, 840 Saga, Japan;(2) Research Institute of Advanced Molecular Science, and Department of Molecular Science and Technology, Graduate School of Engineering, Kyushu University 86, 6-1 Kasuga-kohen, 816 Kasuga-shi, Fukuoka, Japan;(3) Donald P. and Katherine B. Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, 90089-1661 Los Angeles, California, USA |
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Abstract: | Nafion-H, a perfluorinated resinsulfonic acid, catalyzes condensation of acetophenones to provide 1,3,5-triarylbenzenes under relatively mild conditions. Reaction are clean, and water formed as by-product does not deactivate the catalyst. However, ortho-substituted |
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Keywords: | Solid superacids Nafion-H catalyst 1,3,5-triarybenzenes |
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