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Nafion-H catalyzed condensation of acetophenone derivatives. A preparative route of 1,3,5-Triarylbenzenes [1]
Authors:Takehiko Yamato  Chieko Hideshima  Masashi Tashiro  G. K. Surya Prakash  George A. Olah
Affiliation:(1) Department of Industrial Chemistry, Faculty of Science and Engineering, Saga University, 840 Saga, Japan;(2) Research Institute of Advanced Molecular Science, and Department of Molecular Science and Technology, Graduate School of Engineering, Kyushu University 86, 6-1 Kasuga-kohen, 816 Kasuga-shi, Fukuoka, Japan;(3) Donald P. and Katherine B. Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, 90089-1661 Los Angeles, California, USA
Abstract:Nafion-H, a perfluorinated resinsulfonic acid, catalyzes condensation of acetophenones to provide 1,3,5-triarylbenzenes under relatively mild conditions. Reaction are clean, and water formed as by-product does not deactivate the catalyst. However, ortho-substituted
Keywords:Solid superacids  Nafion-H catalyst  1,3,5-triarybenzenes
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