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Influence of flux treatment on the glass forming ability of Pd-Si binary alloys
Affiliation:1. School of Materials Science and Engineering, Kunming University of Science and Technology, Xuefu RD, Kunming 650093, PR China;2. Key Lab of Advanced Materials in Rare & Precious and Nonferrous Metals (Kunming University of Science and Technology), Ministry of Education, Xuefu RD, Kunming 650093, PR China;1. Institute of Metallurgy and Materials Science, Polish Academy of Sciences, Krakow, Poland;2. AGH University of Science and Technology, International Centre of Electron Microscopy for Materials Science, Faculty of Metals Engineering and Industrial Computer Science, Krakow, Poland
Abstract:Pd81Si19 amorphous alloys were prepared by combination methods of melt spinning and B2O3 flux treatment. A comparison between the ribbons prepared from the fluxed ingots and the non-fluxed ones has been carried out. The result reveals that after fluxing treatment the glass transition temperature of the as-prepared glassy ribbons is reduced while the initial crystallization temperature is enhanced. It results in that the supercooled liquid region (defined as the difference between the initial crystallization temperature and the glass transition temperature) of the glassy alloy treated with fluxing technology has been increased from 31 to 42 K. This shows that fluxing technique can enhance the glass forming ability (GFA) of the binary alloy and improve the thermal stability of supercooled liquid of the glassy alloy.
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