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氧化法对玉米黄浆的脱色工艺研究
引用本文:艾艳宁,张庆,李慧霞. 氧化法对玉米黄浆的脱色工艺研究[J]. 合成纤维, 2009, 38(12): 22-25
作者姓名:艾艳宁  张庆  李慧霞
作者单位:东华大学化学化工与生物工程学院,上海,201620;上海市纺织科学研究院,上海,200082
摘    要:玉米黄浆是玉米淀粉生产中产生的主要下脚料,其中大约含有60%的蛋白质。为了合。理利用这些蛋白质,对玉米黄浆的脱色工艺进行了研究,并初步探讨了其在蛋白质复合纤维上的应用。首先,筛选出脱色效果较好的H2O2做为氧化性脱色剂;其次,探讨H2O2脱色工艺中反应浓度、时间、温度及pH值对脱色效果的影响,并由正交试验得出脱色处理最佳工艺为:H2O2浓度为70g/L,pH值为8,反应温度为70℃,反应时间为60min。由红外谱图可以看出脱色前后浆液中蛋白质基本无明显变化.脱色后浆液纺制的蛋白质复合纤维白度明显提高,断裂强度和断裂伸长率均略低于原浆液纺制的纤维。

关 键 词:玉米黄浆  氧化脱色  蛋白质复合纤维

Study on Oxidize Decoloration Techuology of Maize Paste
AI Yan-ning,ZHANG Qing,LI Hui-xia. Study on Oxidize Decoloration Techuology of Maize Paste[J]. Synthetic Fiber in China, 2009, 38(12): 22-25
Authors:AI Yan-ning  ZHANG Qing  LI Hui-xia
Affiliation:AI Yan-ning, ZHANG Qing, LI Hui-xia (1. College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China; 2. Shanghai Textile and Research Institute, Shanghai 200082, China)
Abstract:Maize paste is the main waste of corn starch production,which contains approximately 60%corn protein.In order to use these protein properly,decoloration technology of oxidize agents on maize paste was studied,and its application in the spinning of composite protein fiber was briefly discussed.Firstly, H_2O_2 was selected as an effective oxidative bleaching agents.Secondly,the effect of react concentration, time,temperature and pH value on the bleaching effect during the H_2O_2 bleaching process were explored. Through the orthogonal experiment,the optimum decolorization process was obtained as follows:H_2O_2 concentration 70 g/L,pH value 8,70℃and 60 min.As can be seen from the infrared spectra,there was basically no significant change in the protein before and after bleaching.After bleaching,the composite fiber which was spun by maise paste markedly improved whiteness,while breaking strength and breaking elongation were slightly lower than that of original composite fiber.
Keywords:maize paste  oxidize decoloration  protein composite fiber
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