The Influence of Structural Parameters on the Reactivity of Model Complexes for Compound II: A Mini Review |
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| Authors: | Dorota Rutkowska-Zbik Agnieszka Drzewiecka-Matuszek Malgorzata Witko |
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| Affiliation: | 1. Jerzy Haber Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, ul. Niezapominajek 8, 30-239, Krakow, Poland
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| Abstract: | The present brief review aims at elucidation of the parameters affecting the properties and reactivity of high valent iron(IV) oxo porphyrin complexes, being models of compound II reactive intermediate known from biochemistry of cytochromes and peroxidases. The stress is put on the influence of the axial ligand and porphyrin ring substituents, with special attention on implications for their catalytic activity. |
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