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Modeling the axial distribution of mass transfer coefficient in an agitated-pulsed extraction column |
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| Authors: | Boren Tan Ziyang Xu Yong Wang Yanlin Zhang Yongqi Hu Tao Qi |
| Affiliation: | 1. National Engineering Research Center of Green Recycling for Strategic Metal Resources, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, China;2. National Engineering Research Center of Green Recycling for Strategic Metal Resources, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, China University of Chinese Academy of Sciences, Beijing, China Contribution: Data curation (equal), Formal analysis (equal), Validation (equal);3. Zhongke Nanjing Institute of Green Manufacturing Industry, Chinese Academy of Sciences, Nanjing, China Contribution: Conceptualization (equal), Supervision (equal), Writing - original draft (equal);4. Hebei University of Science and Technology, Shijiazhuang, China Contribution: Supervision (equal), Validation (equal), Writing - review & editing (equal) |
| Abstract: | The dispersed phase holdup and drop size in solvent extraction columns vary along the column height and this affects the mass transfer coefficient and interfacial area. In this article, mass transfer study was performed experimentally using a 25 mm diameter agitated pulsed column. The axial distribution of mass transfer coefficient was determined by coupling population balance equation and axial dispersion model by taking the longitudinal variation in hydrodynamic performance into consideration. Feasibility of different mass transfer models in predicting concentration profiles was evaluated and a novel correlation based on effective diffusivity was developed. The results showed that both overall and volumetric mass transfer coefficients have significant change along the column height and greatly depends on the agitation speed and pulsation intensity. Increasing dispersed phase velocity also augments the overall mass transfer coefficient. The maximum number of transfer unit was measured to be 10 m−1 at agitation speed of 1000 rpm. |
| Keywords: | agitated-pulsed extraction column axial dispersion model interfacial area mass transfer coefficient population balance |