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离子液体在纳米ZnO材料制备中的研究进展
引用本文:陈婷婷,尹炯婷,许映杰.离子液体在纳米ZnO材料制备中的研究进展[J].化工学报,2021,72(5):2436-2447.
作者姓名:陈婷婷  尹炯婷  许映杰
作者单位:绍兴文理学院化学化工学院,浙江绍兴312000
基金项目:国家自然科学基金项目(21978172);浙江省自然科学基金项目(Y18B060014);浙江省大学生科技创新项目(2019R432023)
摘    要:离子液体(ILs)具有蒸气压低、液程宽、热稳定性好、结构和性质可调节等特点, 作为反应溶剂、模板剂或结构导向剂等在纳米材料制备领域得到了广泛的应用。纳米ZnO在传感器、太阳能电池、光催化和发光二极管等领域具有广泛的应用。总结了近年来ILs在纳米ZnO材料制备中的研究进展, 重点归纳和比较了常规非质子型ILs、质子型ILs、碱性ILs和聚ILs在制备纳米ZnO中的应用,及其调控纳米ZnO形貌、尺寸和性能的作用特点, 并为今后ILs应用于金属纳米材料的制备提出了建议。

关 键 词:离子液体  氧化锌  纳米材料  制备  纳米粒子
收稿时间:2020-10-09

Research progress of ionic liquids in preparation of ZnO nanomaterials
CHEN Tingting,YIN Jiongting,XU Yingjie.Research progress of ionic liquids in preparation of ZnO nanomaterials[J].Journal of Chemical Industry and Engineering(China),2021,72(5):2436-2447.
Authors:CHEN Tingting  YIN Jiongting  XU Yingjie
Affiliation:College of Chemistry and Chemical Engineering, Shaoxing University, Shaoxing 312000, Zhejiang, China
Abstract:Ionic liquids (ILs) are a new type of green solvent, which have been widely used in the field of nanomaterial preparation as a solvent, template or structure directing agent due to their unique properties, such as low vapor pressure, wide liquid temperature range, non-flammability, chemical stability and tunable structure and properties. Nano-ZnO materials have a wide range of applications in the field of sensors, solar cells and photocatalysis. The research progress of ILs in the preparation of nano-ZnO materials in recent years is summarized. The applications of traditional aprotic ILs, protic ILs, basic ILs and poly(ionic liquid)s in the synthesis of nano-ZnO materials are compared and analyzed, as well as their roles in regulating the morphology, particle size and properties of nano-ZnO. And put forward suggestions for the future application of ILs in the preparation of metal nanomaterials.
Keywords:ionic liquids  zinc oxide  nanomaterials  preparation  nanoparticles  
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