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催化汽油和C4烃类在LBO-A催化剂上芳构化反应的实验研究
引用本文:闫平祥,高金森,徐春明.催化汽油和C4烃类在LBO-A催化剂上芳构化反应的实验研究[J].工业催化,2005,13(4):13-17.
作者姓名:闫平祥  高金森  徐春明
作者单位:石油大学(北京)重质油国家重点实验室,北京102249
摘    要:在小型固定流化床实验装置上,单独利用催化裂化提高辛烷值助剂LBO-A为催化剂,分别对催化汽油和C4烃类进行了催化转化反应的实验研究,考察了反应温度和空速对反应产物分布和组成的影响。实验结果表明,LBO-A单独作为催化剂对催化汽油和C4烃类具有较强的芳构化性能,同时,所产裂化气体中,丙烯含量远高于普通裂化催化剂。因此,在适宜的反应条件下,可生产高辛烷值的汽油组分,同时,增产丙烯,并且这两种性能随反应温度的升高而增强。

关 键 词:催化汽油  C4烃类  芳构化  芳烃  丙烯  
文章编号:1008-1143(2005)04-0013-05
修稿时间:2004年10月19

Laboratory studies on aromatization of gasoline and C4 hydrocarbons on LBO-A catalyst
YAN Ping-xiang,GAO Jin-sen,XU Chun-ming.Laboratory studies on aromatization of gasoline and C4 hydrocarbons on LBO-A catalyst[J].Industrial Catalysis,2005,13(4):13-17.
Authors:YAN Ping-xiang  GAO Jin-sen  XU Chun-ming
Affiliation:The State Key Laboratory of Heavy Oil Processing, University of Petroleum(Beijing),; Beijing 102249, China
Abstract:Catalytic aromatization of FCC (Fluid Catalytic Cracking) gasoline and C_4 hydrocarbons on LBO-A catalyst, a RON-enhancing additive for conventional FCC catalysts, were studied in a small fixed-fluidized bed reactor, using gasoline and C_4 hydrocarbons as the feed, respectively. Influences of reaction temperature and space velocity on distribution and composition of the products were investigated. The experimental results showed that LBO-A, solely as the catalyst, has relatively strong aromatization activity for aromatization of gasoline and C_4 hydrocarbons, with higher propylene content in the LPG (liquefied petroleum gas) than conventional FCC catalysts. Production of high-RON gasoline and increasing yield of propylene can be realized over LBO-A catalyst under appropriate reaction condition. The activity for production of high-RON gasoline and increasing yield of propylene increases with temperature.
Keywords:FCC gasoline  C_4 hydrocarbons  aromatization  high-RON gasoline  increasing propylene yield
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