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含钌废催化剂回收钌的技术综述
引用本文:肖玉旋,史建公,苏海霞,张毅,苑志伟,魏珍. 含钌废催化剂回收钌的技术综述[J]. 贵金属, 2023, 44(1): 81-85
作者姓名:肖玉旋  史建公  苏海霞  张毅  苑志伟  魏珍
作者单位:中国石化催化剂有限公司工程技术研究院,北京 101111;河北北方学院 理学院,河北 张家口 075000
摘    要:从废钌催化剂中回收钌对于钌资源缺乏的我国具有特殊意义。基于文献和国内相关专利的分析,对氧化蒸馏法、熔融还原沉淀法、离子交换法、吸附法、捕集法、萃取法以及其他回收钌的方法进行了综述分析。不同方法各有其优缺点,其中成熟和应用最广的是氧化蒸馏法,选择性吸附法和萃取法具有选择性高、回收率高、污染小,是有发展前景的技术。

关 键 词:有色金属冶金;废催化剂;钌;回收技术;综述
收稿时间:2022-03-03

A review on ruthenium recovery from ruthenium-containing waste catalysts
XIAO Yuxuan,SHI Jiangong,SU Haixi,ZHANG Yi,YUAN Zhiwei,WEI Zhen. A review on ruthenium recovery from ruthenium-containing waste catalysts[J]. Precious Metals, 2023, 44(1): 81-85
Authors:XIAO Yuxuan  SHI Jiangong  SU Haixi  ZHANG Yi  YUAN Zhiwei  WEI Zhen
Affiliation:Institute of Engineering & Technology of SCC, Beijing 101111, China;School of Science, Hebei North University, Zhangjiakou 075000, Hebei, China
Abstract:It is of special significance to recover ruthenium from spent ruthenium catalysts in China. The sources of ruthenium-containing waste generally include waste catalyst, nuclear waste, alloy materials, and so on. Based on the literature and relevant domestic patents, several important methods to recover ruthenium from the waste catalysts are described. and the advantages and disadvantages ofeach method are also analyzed. These methods are oxidation distillation, melting reduction precipitation, ion exchange, adsorption, capture, extraction. Among them, oxidation distillation is the most mature and widely used. Selective adoption method and extraction method are promising, because they have the advantages of high selectivity, high recovery rate and low pollution.
Keywords:nonferrous metallurgy   waste catalyst   ruthenium   recovery technology   review
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