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锂离子电池正极材料热稳定性研究进展
引用本文:曹笃盟,李志友,周科朝. 锂离子电池正极材料热稳定性研究进展[J]. 粉末冶金材料科学与工程, 2003, 8(3): 224-230
作者姓名:曹笃盟  李志友  周科朝
作者单位:中南大学粉末冶金国家重点实验室,湖南,长沙,410083
基金项目:国家自然科学基金(50002015)
摘    要:综述了锂离子电池正极材料热稳定性的研究现状及其进展。针对正极材料LiCoO_2,LiNiO_2,LiMn_2O_4及其衍生物的热稳定性,众多研究者提出了不同的反应机理,认为正极材料的热稳定性与颗粒大小、晶体结构、充/放电状态、脱锂程度及电解质性质等因素有关。可以利用掺杂技术、涂层技术及优化合成条件等手段来改善正极材料的热稳定性。

关 键 词:锂离子电池  热稳定性  正极材料
修稿时间:2003-04-18

Development of thermal stability of positive materials for lithium-ion batteries
CAO Du-meng,LI Zhi-you,ZHOU Ke-chao. Development of thermal stability of positive materials for lithium-ion batteries[J]. materials science and engineering of powder metallurgy, 2003, 8(3): 224-230
Authors:CAO Du-meng  LI Zhi-you  ZHOU Ke-chao
Abstract:The current researches and developments of thermal stability of positive materials for lithium-ion batteries are reviewed in the paper. Emphasizing on thermal stability of LiCoO_2, LiNiO_2, LiMn_2O_4 and their derivatives, researchers have introduced many different mechanisms. They think the thermal stability is related to some factors such as particle size, crystal structure, charge/discharge, the extent of delithiated,electrolytes. In order to improve the thermal stability of positive materials,doping ,coating and optimizing synthetic methods may be used.
Keywords:lithium-ion battery  thermal stability  positive material
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