Synthesis and structure of a dimeric scandium bis(μ-methoxy) complex |
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| Authors: | Simon A. Cotton Victoria M.A. Fisher Paul R. Raithby Stefanie Schiffers Simon J. Teat |
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| Affiliation: | aUppingham School, Uppingham, Rutland LE15 9QE, UK;bDepartment of Chemistry, University of Bath, Bath, BA2 7AY, UK;cCCLRC Daresbury Laboratory, Daresbury, Warrington WA4 4AD, UK |
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| Abstract: | Reaction of hydrated scandium nitrate with 1,10-phenanthroline (phen) in methanol leads to formation of the unusual dimeric complex [(phen)(NO3)2Sc(μ-OMe)2Sc(NO3)2(phen)], in which the scandium centres are eight co-ordinate. The complex features two bridging methoxy ligands, as well as bidentate nitrates and chelating 1,10-phenanthroline ligands. |
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| Keywords: | Crystal structure Scandium complex Eight co-ordinate complex Nitrate complex Alkoxide group |
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