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150 t LF精炼喂钙线处理钢中夹杂物的演变
引用本文:姜玉龙,郑万,齐盼盼,李天佑,王春锋,刘炳宇,李光强.150 t LF精炼喂钙线处理钢中夹杂物的演变[J].特殊钢,2016,37(3):8-12.
作者姓名:姜玉龙  郑万  齐盼盼  李天佑  王春锋  刘炳宇  李光强
作者单位:武汉科技大学1省部共建耐火材料与冶金国家重点实验室; 2钢铁冶金及资源利用省部共建教育部,重点实验室,武汉430081 ; 3武汉钢铁股份有限公司,武汉430083
基金项目:国家自然科学基金资助(No. 51541409)
摘    要:通过热力学计算和扫描电镜研究了铁水预处理-150 t BOF-钢包吹氩-LF-CSP流程LF精炼后喂硅钙线和钙铝线处理的Q235,SPA-H和DC01钢中夹杂物演变及精炼渣对其影响。结果表明,Ca处理前的精炼过程中,钢中Al2O3大部分已经被精炼渣(/%:52.97~55.63CaO,4.11~12.78SiO2,5.11~9.87MgO,22.93~31.72Al2O3,0.58~1.27FeO,0.01~0.07MnO)改性为MgO·Al2O3,根据Mg-Al-O生成优势区图,钢中有微量Mg就能使Al2O3变性为MgO·Al2O3尖晶石,钙处理主要是对MgO·Al2O3尖晶石的变性,因此需要保证充足的钙线喂入量,才能将高熔点铝镁和铝镁钙复合夹杂物变性到低熔点区域;为了避免生成高熔点CaS夹杂物,钙处理前Al]=0.02%~0.04%时,S]要小于0.001 4%。 

关 键 词:钙处理  Q235  DC01  SPA-H钢  夹杂物  CSP  水口堵塞  精炼渣  
收稿时间:2015-12-30

Evolution of Inclusions in Steel with 150 t LF Refining Feeding Calcium Wire Treatment
Jiang Yulong,Zheng Wan,Qi Panpan,Li Tianyou,Wang Chunfeng,Liu Bingyu,Li Guangqiang.Evolution of Inclusions in Steel with 150 t LF Refining Feeding Calcium Wire Treatment[J].Special Steel,2016,37(3):8-12.
Authors:Jiang Yulong  Zheng Wan  Qi Panpan  Li Tianyou  Wang Chunfeng  Liu Bingyu  Li Guangqiang
Affiliation:1 State Key Lab of Refractories & Metallurgy; 2 Key Lab for Ferrous Metallurgy and Resources Utilization of Ministry of Education,Wuhan University of Science and Technology, Wuhan 430081 ; 3 Wuhan Iron and Steel Co Ltd, Wuhan 430083
Abstract:The evolution of inclusions in steel Q235, SPA-H and DC01 treated by feeding silicon-calcium wire and calcium-aluminium wire after LF refining in metal pretreatment-150 t BOF-ladle argon blowing-LF-CSP flowsheet and the effect of refining slag on inclusions are studied by thermodynamic calculation and scanning electron microscope. The results show that during refining process before Ca treatment the greater part of Al2O3 in steel is modified to MgO·Al2O3 by refining slag (/%: 52.97 ~55.63CaO, 4.11 ~12.78SiO2, 5.11~9.87MgO, 22.93 ~31.72Al2O3, 0. 58 ~1.27FeO, 0. 01 ~0. 07MnO) ; based on the Mg-Al-O predominant forming diagram, with micro-amount Mg in steel the Al2O3 may modify to MgO· Al2O3 spinel, the calcium treatment is mainly to modify the MgO· Al2O3 spinel, therefore it is need to feeding sufficient amount of calcium for high melting point aluminium-magnesium and aluminium-magnesium-calcium inclusion modifying to low melting point region; in order to avoid forming high melting point CaS inclusions, before calcium treatment with Al] =0. 02% ~0. 04% the S] should be less than 0.001 4%.
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