Preparation and characterization of polyethylene (PE)/clay nanocomposites by <Emphasis Type="Italic">in
situ</Emphasis> polymerization with vanadium-based intercalation catalyst |
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Authors: | Liqiang Cui Seong Ihl Woo |
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Affiliation: | (1) Department of Chemical and Biomolecular Engineering & Center for Ultramicrochemical Process Systems (CUPS), Korea Advanced Institute of Science and Technology, 373-1 Guseong-dong, 305-701 Yuseong-gu, Daejeon, Republic of Korea |
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Abstract: | Summary Complete exfoliation of clay during vanadium-based Zigler-Natta polymerization of ethylene has been
successfully carried out by using clay and MgCl2 hybrid supports. MgCl2
offers catalyst loading sites, and the vanadium catalyst is avoided directly anchoring in the surface
of the clay, so intercalation catalyst clay/MgCl2/VOCl3displays
high activity for ethylene polymerization. Exfoliated PE/clay nanocomposites are confirmed by X-ray
diffraction (XRD), and transmission electron microscopy (TEM). Strong interaction between the dispersed
clay particles and the polymer matrices provides good thermal and mechanical properties. Compared with
pure PE, all these nanocomposites show enhancement of the melting temperature (Tm)
and the thermal decomposition temperatures. Additionally, the incorporation of clay into the PE matrix
significantly improves the mechanical properties of these nanocomposites. The increased tensile strength
has been observed in the range of 3.4 to 7.9 MPa. The tensile moduli of the PE/clay nanocomposite
are 23.4%-45.3% higher than that of the pure PE. |
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