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不同煤气化过程的FT合成油-电多联产模拟计算
引用本文:于戈文,徐元源,郝栩,李永旺. 不同煤气化过程的FT合成油-电多联产模拟计算[J]. 过程工程学报, 2009, 9(3): 545-551
作者姓名:于戈文  徐元源  郝栩  李永旺
作者单位:中国科学院山西煤炭化学研究所煤转化国家重点实验室,山西,太原,030001;中国科学院研究生院.北京,100049;中国科学院山西煤炭化学研究所煤转化国家重点实验室,山西,太原,030001
基金项目:国家自然科学基金,国家重点基础研究发展规划(973计划),国家杰出青年科学基金 
摘    要:设计并模拟了以Shell, GSP, Texaco煤气化为气头的FT合成油-电多联产系统,考察了三者的系统特性. 结果表明,在入炉煤量为1000 t/h的条件下,其合成油(包括柴油、石脑油和LPG)产量分别为318.56, 318.42和285.79 t/h,但FT合成96%的CO转化率使其发电量均不足以满足系统自身的用电,尾气发电仅相当于回收了原料煤热值近2%的能量. 以Shell技术为气头的多联产系统具有最高的系统热效率(47.65%),Texaco技术为气头的多联产系统具有最低的系统热效率,比前者低6.5%左右. 3种方案捕获的CO2分别相当于回收了进入系统全部碳含量的58.69%, 58.65%, 59.55%.

关 键 词:煤气化  FT合成  联合循环  多联产  模拟
收稿时间:2008-12-26
修稿时间:2009-03-11

Simulation for Polygeneration Systems of FT Synfuels-Power Based on Different Gasification Processes
YU Ge-wen,XU yuan-yuan,HAO Xu,LI Yong-wang. Simulation for Polygeneration Systems of FT Synfuels-Power Based on Different Gasification Processes[J]. Chinese Journal of Process Engineering, 2009, 9(3): 545-551
Authors:YU Ge-wen  XU yuan-yuan  HAO Xu  LI Yong-wang
Affiliation:State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of SciencesState Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of SciencesState Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of SciencesState Key Laboratory of Coal Conversion, Institute of Coal Chemistry,Chinese Academy of Sciences
Abstract:Polygeneration systems of FT synfuels-power based on Shell, GSP and Texaco gasification are designed and simulated. The characters of systems are also assessed. The results show that under the condition of 1000 t/h designed rate of coal feedstock, the yields of synfuels, diesel, naphtha and LPG, are 318.56, 318.42 and 285.79 t/h, respectively. However, the electricity generation does not meet the needs of systems because of 96% of CO conversion rate for FT synthesis. The generated electricity is equivalent to recovery of 2% of coal thermal value. 47.65% of the highest system thermal efficiency comes from the polygeneration based on the Shell gasification. The lowest system thermal efficiency, resulting from the polygeneration based on the Texaco gasification, has decreased 6.5% compared with the former. The proportion of carbon capture to the total carbon entering the systems is 58.69%, 58.65% and 59.55%, respectively.
Keywords:coal gasification  Fischer-Tropsch synthesis  combined cycle  polygeneration  simulation  
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