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软木纤维蒸汽闪爆改性及其形态结构表征
引用本文:邵自强,廖双泉,马凤国,吕秉峰,谭惠民. 软木纤维蒸汽闪爆改性及其形态结构表征[J]. 高分子材料科学与工程, 2002, 18(2): 120-122
作者姓名:邵自强  廖双泉  马凤国  吕秉峰  谭惠民
作者单位:1. 北京理工大学化工与材料学院,北京,100081
2. 华北工学院化学工程系,山西,太原,030051
基金项目:中国博士后员基金资助项目
摘    要:研究采用高压热蒸汽闪爆技术,对软木纤维进行物理改性,通过对闪爆前后纤维素表征分析,结果发现,高压闪爆再生的纤维素形态,聚合度,在稀碱中的溶解度有极大改变,因原纤形态的差异,几种纤维素的闪爆改性的难易程度为,麻,棉,硬木,软木,经过一定压力及温度闪爆可得到在NaOH碱溶液中完全溶解的软木纤维,这一结果可使粘胶工业实现稀碱溶液直接湿纺的技术。

关 键 词:软木纤维 蒸汽闪爆 改性 溶解度 粘胶纤维 形态结构 表征
文章编号:1000-7555(2002)02-0120-03
修稿时间:2000-06-18

STUDY ON STRUCTURAL CHANGES OF SOFT WOOD CELLULOSES TREADED BY THE STEAM EXPLOSION
SHAO Zi qiang ,LIAO Shuang quan ,MA Feng guo ,LU Bing feng ,TAN Hui min. STUDY ON STRUCTURAL CHANGES OF SOFT WOOD CELLULOSES TREADED BY THE STEAM EXPLOSION[J]. Polymer Materials Science & Engineering, 2002, 18(2): 120-122
Authors:SHAO Zi qiang   LIAO Shuang quan   MA Feng guo   LU Bing feng   TAN Hui min
Affiliation:SHAO Zi qiang 1,LIAO Shuang quan 1,MA Feng guo 1,LU Bing feng 2,TAN Hui min 1
Abstract:Soft wood celluloses were treaded by high pressure and temperature steam explosion. Morphology, solubility towards aqueous alkali solution, degree of polymerization of original and regenerated celluloses were analyzed. Results indicate that sensitivity of celluloses on steam explosion decreases in the following order:soft wood>hard wood>cotton fiber>hemp fiber. On certain conditions though which the steam explosion makes natural softwood completely soluble in aqueous alkali solution. The results make possible that novel fiber spun can be gained from aqueous alkali solution of soft wood cellulose by wet spinning method in the regenerated cellulose fiber industry.
Keywords:soft wood cellulose  steam explosion  solubility  cellulose fiber
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