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电解液对棉秆基活性炭超级电容器性能的影响
引用本文:陈铭德,吐尔迪·吾买尔,康雪雅,宋怀河,张璐,王欢欢.电解液对棉秆基活性炭超级电容器性能的影响[J].电池工业,2013,18(1):62-66.
作者姓名:陈铭德  吐尔迪·吾买尔  康雪雅  宋怀河  张璐  王欢欢
作者单位:1. 中国科学院新疆理化技术研究所,新疆乌鲁木齐830011;中国科学院大学,北京100049
2. 中国科学院新疆理化技术研究所,新疆乌鲁木齐,830011
3. 北京化工大学,北京,100029
基金项目:新疆维吾尔自治区科技支疆项目计划(指令性)项目,中国科学院知识创新工程重要方向项目
摘    要:以棉秆基活性炭为超级电容器电极材料,1 mol/L的Et4NBF4/AN和1 mol/LLiPF6/(EC+DMC+DEC)为电解液,组装成模拟纽扣式超级电容器,采用恒流充放电、循环伏安、交流阻抗对其电化学性能进行测试,研究不同电解液对棉秆基活性炭电极电容器性能的影响.结果表明,棉秆基活性炭电极材料在Et4 NBF4/AN有机电解液中电化学性能优于其在LiPF6/(EC+DMC+DEC)电解液中,在2 A/g的电流密度下,放电比容量高达98 F/g,循环1000次后,容量没衰减.

关 键 词:超级电容器  棉秆基活性炭  电解液  比电容

Effect of different electrolytes on the performance of supercapacitor with cotton stalk based activated carbon
CHEN Ming-de , TUERDI·Wumaier , KANG Xue-ya , SONG Huai-he , ZHANG Lu , WANG Huan-huan.Effect of different electrolytes on the performance of supercapacitor with cotton stalk based activated carbon[J].Chinese Battery Industry,2013,18(1):62-66.
Authors:CHEN Ming-de  TUERDI·Wumaier  KANG Xue-ya  SONG Huai-he  ZHANG Lu  WANG Huan-huan
Affiliation:1. Key Laboratory of Functional Materials and Devices under Special Environments, CAS ,Xinjiang Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Urumqi , Xinjiang 830011 ,China 2. Graduate University of Chinese Academy of Sciences, Beij ing 100049 ,China;3. Advanced Carbon Materials Research Laboratory, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 10002 ,China)
Abstract:Supercapacitors were prepared with activated carbon derived from cotton stalk as elec- trode and using 1 mol/L Et4NBF4/AN, LiPFG/(EC-PDMC+DEC) as organic electrolytes, re- spectively. The effects of symmetric ammonium electrolyte on the capacitance performance of ac- tivated carbon electrode were studied by galvanostantic charge/discharge, cycle voltammetry and AC impedance. The results indicated that it had higher discharge capacitance in 1 mol/L Et4 NBF4/AN organic electrolyte. The specific capacitance of activated carbon was 98 F/g at the current density of 2 A/g, the electrode exhibited excellent stability after 1000 cycles without any loss of capacity.
Keywords:supercapacitor  activated carbon  electrolyte  specific capacity
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