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铝电解电容器用电解液的烧煮工艺研究
引用本文:胡拥军,周向前,龙立平,周攀登. 铝电解电容器用电解液的烧煮工艺研究[J]. 电池工业, 2013, 18(1): 14-17
作者姓名:胡拥军  周向前  龙立平  周攀登
作者单位:湖南城市学院化学与环境工程学院,湖南益阳,413000
基金项目:湖南省教育厅重点研究项目,湖南省科技计划项目,湖南省教育厅科研项目
摘    要:以现有生产工艺为基础,通过调整配方,改进烧煮工艺,用正交试验研究中高压铝电解电容器用工作电解液.结果表明,通过添加不同分子量的高分子聚合物PVA,可以提高电解液的闪火电压,降低闪火时间.当以乙二醇为主溶剂,癸二酸铵、十二双酸铵、壬二酸氢铵、硼酸等为主溶质,添加1.15%(质量百分数)的高分子聚合物时,32s初闪电压为428 V,电解液64s时闪火电压达到500 V,制作的电容器(400 V、6.8μF)漏电流为13.5μA,损耗0.05,耐纹波寿命达到8kh.

关 键 词:铝电解电容器  电解液  闪火电压  正交试验

Study on the heating technology of electrolyte for aluminum electrolytic capacitor
HU Yong-jun , ZHOU Xiang-qian , LONG Li-ping , ZHOU Pan-deng. Study on the heating technology of electrolyte for aluminum electrolytic capacitor[J]. Chinese Battery Industry, 2013, 18(1): 14-17
Authors:HU Yong-jun    ZHOU Xiang-qian    LONG Li-ping    ZHOU Pan-deng
Affiliation:(Department of Chemistry, Hunan City University, Yiyang , Hunan 413000, China)
Abstract:Based on the existing process, orthogonal test is used to research a working electrolyte for high-voltage aluminum electrolytic capacitors by adjusting the formula and improving the heating technology. The results show that adding the high molecular polymer PVA into the elec- trolyte can raise the sparking voltage and reduce sparking time. When ethylene is selected as sol- vent, ammonium sebacate, double twelve acid amine and boric acid as solutes, and the PVA is 1.15% (wt), the initial sparking voltage of working electrolyte reaches to 428V(38 seconds), and its sparking time for 500 V is 64 seconds. The leakage current and loss of aluminum electrolytic capacitors(400 V, 6.8 μF)prepared with the electrolyte is 13.5 μA and 0. 05 , respectively. The electrolytic capacitors can get through the test for 8000 h under ripple current.
Keywords:aluminum electrolytic capacitors  working electrolyte  sparking voltage  orthogonaltest
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