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Temperature enhanced gas sensing properties of diamond films
Authors:Marina Davydova  Martin StuchlikBohuslav Rezek  Alexander Kromka
Affiliation:a Institute of Physics, Academy of Science of the Czech Republic, Cukrovarnicka 10, 16253 Prague, Czech Republic
b Department of Physics, Faculty of Civil Engineering, CTU in Prague, Thakurova 7, 16629 Prague, Czech Republic
c Department of Chemistry, TU Liberec, Studentska 2, 46117 Liberec, Czech Republic
Abstract:Nanocrystalline diamond (NCD) film was used as a functional part of gas sensor. The gas sensing properties of H-terminated nanocrystalline diamond films were examined to oxidizing gases (i.e., COCl2 and humid air). Pronounced increase in the surface conductivity (3 orders of magnitude) was found after sensor exposure to phosgene gas and was explained by the surface transfer doping effect. We also present a possible way how to achieve sensor selectivity, i.e. how to distinguish between phosgene and humid air (the mostly present background gas in a common environment).
Keywords:Nanocrystalline diamond  Phosgene  Surface conductivity  Gas sensor  SEM
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