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MnO/C core-shell nanorods as high capacity anode materials for lithium-ion batteries
Authors:Bing SunZhixing Chen  Hyun-Soo KimHyojun Ahn  Guoxiu Wang
Affiliation:a School of Chemistry and Forensic Science, University of Technology Sydney, Broadway, Sydney, NSW 2007, Australia
b School of Mechanical, Materials and Mechatronic Engineering, University of Wollongong, Wollongong, NSW 2522, Australia
c Battery Research Centre, Korean Electrotechnology Research Institute, Changwon 641-120, Republic of Korea
d School of Materials Science and Engineering, Gyeongsang National University, 900 Gazwa-dong, Jinju, Gyeongnam 660-701, Republic of Korea
Abstract:MnO/C core-shell nanorods were synthesized by an in situ reduction method using MnO2 nanowires as precursor and block copolymer F127 as carbon source. Field emission scanning electron microscopy and transmission electron microscopy analysis indicated that a thin carbon layer was coated on the surfaces of the individual MnO nanorods. The electrochemical properties were evaluated by cyclic voltammetry and galvanostatic charge-discharge techniques. The as-prepared MnO/C core-shell nanorods exhibit a higher specific capacity than MnO microparticles as anode material for lithium ion batteries.
Keywords:Core-shell nanostructure   Nanorods   Manganese mono-oxide   Anode materials   Lithium ion batteries
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