Acylation and oxidation of primary amines and alcohols catalyzed by nanoporous polyaniline emeraldine salt |
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| Authors: | Chan Woo Lee Ho Yun Hwang Han Mo Jeong Ung Chan Yoon Ki-Whan Chi |
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| Affiliation: | aDepartment of Chemistry, University of Ulsan, Nam Gu, Ulsan 680-749, Republic of Korea;bDepartment of Chemistry, Pusan National University, Busan 609-735, Republic of Korea |
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| Abstract: | We described the convenient and efficient catalytic acylation and oxidation of primary amines and alcohols compounds into amide/ester or aldehyde compounds using nanoporous polyaniline emeraldine salts catalysts. The reaction mechanism of acylation by polyaniline emeraldine salt catalyst is explained by acid catalyzed addition–elimination reaction, whereas oxidation process is proposed to occur through a radical pathway. |
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| Keywords: | Polyaniline catalyst Emeraldine salt Acylation Oxidation Amine Alcohol |
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