Modelling of microporous diffusion of n-paraffins in zeolite 5A |
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Authors: | Liljana T Markovska Vera D Meshko Radmila T Kiprijanova |
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Affiliation: | (1) Faculty of Technology and Metallurgy, University “St.Cyril and Methodius, Skopje, Republic of Macedonia |
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Abstract: | Sorptive liquid-phase diffusion of two n-paraffins, C10H22 and C11H24, dissolved in isooctane, onto micropore of 5A zeolite was studied to assess multicomponent diffusion and competitive effects.
Diffusion coefficients for adsorbing components are determined from experimental batch reactor data. The experimental data
indicate that diffusion through the microporous zeolite crystals is the primary diffusional resistance. A mathematical model
of the rate of adsorption of a solute from a liquid by micropore adsorbent in a batch system was developed. The equation describing
the mass transport by diffusion in a micropore adsorbent has been solved in order to obtain theoretical uptake curves for
systems when the adsorption equilibrium isotherm is the favourable and nonlinear one. A computer simulation of the microporous
diffusion is performed by use of the ISIM-Interactive Simulation Language. The effect of main term and cross-term coefficients
of micropore diffusion for the system considered is investigated. |
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Keywords: | Multicomponent Diffusion Zeolite Micropore Diffusion |
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