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PVC/环氧树脂F51共混物性能的研究(二)
引用本文:钱志军,张敏,洪升,徐明,王彩红,鲁圣军. PVC/环氧树脂F51共混物性能的研究(二)[J]. 聚氯乙烯, 2012, 40(10): 16-19,26
作者姓名:钱志军  张敏  洪升  徐明  王彩红  鲁圣军
作者单位:1. 金发科技股份有限公司,广东广州,510520
2. 贵州大学材料与冶金学院,贵州贵阳,550025
基金项目:贵阳市工业振兴科技计划项目
摘    要:以554/504为固化剂,研究了不同固化时间下,F51用量对PVC/F51共混物的微观形貌、力学性能和维卡软化温度的影响。结果表明:①少量的F51在PVC基体中分散比较均匀,F51用量较多时会出现团聚现象;②少量的F51有利于提高PVC/F51共混物的力学性能和维卡软化温度,用量以2~6份为宜;③随着固化时间的延长,PVC/F51共混物的力学性能和维卡软化温度均提高;④固化剂554可进一步提高PVC/F51共混物的拉伸强度和弯曲强度,但会降低缺口冲击强度和维卡软化温度。

关 键 词:PVC  环氧树脂  固化剂  力学性能  维卡软化温度

Study on properties of PVC/epoxy resin F51 composites:part two
QIAN Zhijun,ZHANG Min,HONG Sheng,XU Ming,WANG Caihong,LU Shengjun. Study on properties of PVC/epoxy resin F51 composites:part two[J]. Polyvinyl Chloride, 2012, 40(10): 16-19,26
Authors:QIAN Zhijun  ZHANG Min  HONG Sheng  XU Ming  WANG Caihong  LU Shengjun
Affiliation:1.Blonde Science and Technology Co.,Ltd.,Guangzhou 510520,China; 2.The Material and Metallurgy College,Guizhou University,Guiyang 550025,China)
Abstract:The influences of F51 dosages on the micromorphologies,mechanical properties and Vicat softening temperature of PVC/F51 composites cured by curing agent 554/504 for different time were studied.The resuls showed that: ① a small amount of F51 could uniformly disperse in PVC matrix,and more F51 dosages could lead to the appearance of agglomeration;② a small amount of F51 was of benefit to increasing the mechanical properties and Vicat softening temperature of PVC/F51 composites,and the suitable dosages were 2-6 phr;③ with the prolonging of curing time,the mechanical properties and Vicat softening temperature of PVC/F51 composites were all increased;④ curing agent 554 could further increase the tensile strength and bending strength of PVC/F51 composites,but could decrease its notch impact strength and Vicat softening temperature.
Keywords:PVC  epoxy resin  curing agent  mechanical property  Vicat softening temperature
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