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耐热聚丙烯专用料的结构与性能
引用本文:康文倩,马宗立,高玉林,王雄,杨宝,闫功臣.耐热聚丙烯专用料的结构与性能[J].中国塑料,2020,34(7):10-13.
作者姓名:康文倩  马宗立  高玉林  王雄  杨宝  闫功臣
作者单位:1.中国石油天然气股份有限公司兰州化工研究中心,兰州 7300602.中国石油天然气股份有限公司华南化工销售公司,广州 5100003.中国石油天然气股份有限公司兰州石化公司,兰州 730060
摘    要:采用凝胶色谱仪、升温淋洗分析仪、差示扫描量热仪以及X射线衍射仪对国产耐热聚丙烯H8020和2种进口耐热聚丙烯的结构进行表征,进一步采用熔体流动速率仪、万能材料试验机、摆锤冲击仪以及维卡热变形测定仪对性能进行测定。结果表明,H8020的弯曲强度为39.4 MPa、弯曲模量为1 820 MPa、拉伸强度为37.5 MPa、冲击强度为3.2 kJ/m2,具有良好的刚韧平衡性,热变形温度为115 ℃,维卡软化温度为158 ℃,综合性能达到甚至超过国外同类材料。

关 键 词:耐热聚丙烯  均聚聚丙烯  冲击强度  
收稿时间:2020-02-24

Structure and Performance of Heat?Resistant Polypropylene Special Material
Wenqian KANG,Zongli MA,Yulin GAO,Xiong WANG,Bao YANG,Gongchen YAN.Structure and Performance of Heat?Resistant Polypropylene Special Material[J].China Plastics,2020,34(7):10-13.
Authors:Wenqian KANG  Zongli MA  Yulin GAO  Xiong WANG  Bao YANG  Gongchen YAN
Affiliation:1.PetroChina Lanzhou Petrochemical Research Center, Lanzhou 730060, China2.PetroChina South China Chemicals;Marketing Company, Guangzhou 510000, China3.PetroChina Lanzhou Petrochemical Company, Lanzhou 730060, China
Abstract:The structure of heat?resistant polypropylene special material (H8020) was characterized by gel permeation chromatography, temperature rising elution fractionation, differential scanning calorimetry and X?ray diffractometer, and its mechanical and heat?resistant properties were investigated by melting flow rate instrument, universal material testing machine, pendulum machine and thermal deformation & Vicat softening temperature tester. The results indicated that the heat?resistant polypropylene exhibited the flexural strength of 39.4 MPa, the flexural modulus of 1 820 MPa, the tensile strength of 37.5 MPa and the izod impact strength of 3.2 kJ/m2, presenting a good balance between rigidity and toughness. Moreover, this special material also showed a thermal deformation temperature of 115 °C and a Vicat softening temperature of 158 °C. It is concluded that the comprehensive performance of the domestic product H8020 is superior to that of foreign products.
Keywords:heat?resistant polypropylene  homo?polypropylene  impact strength  
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