加热烟草制品(HTPs)气溶胶成分的MD-GC/MS分析 |
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引用本文: | 刘鸿,陶立奇,陆怡峰,吴达,郑赛晶,陈勇,姚鹤鸣. 加热烟草制品(HTPs)气溶胶成分的MD-GC/MS分析[J]. 中国烟草学报, 2020, 26(3): 9-14. DOI: 10.16472/j.chinatobacco.2019.181 |
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作者姓名: | 刘鸿 陶立奇 陆怡峰 吴达 郑赛晶 陈勇 姚鹤鸣 |
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作者单位: | 1.上海烟草集团有限责任公司, 上海市长阳路717号 200082 |
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基金项目: | 中国烟草总公司项目“加热不燃烧烟草制品(电加热)标准研究”2017QB 006 |
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摘 要: | 目的 了解加热烟草制品(HTPs)气溶胶成分特点。 方法 采用中心切割二维气相色谱-质谱法,对17个典型的HTPs气溶胶成分进行了分析。 结果 (1)HTPs气溶胶的主要成分与普通卷烟烟气相近,但释放量较低,其中66.7%的成分种类在HTPs气溶胶中的每口释放量小于卷烟烟气释放量的10%;(2)HTPs气溶胶中占比最高的成分为甘油(35.8%),烟碱(25.7%),1, 2-丙二醇(10.8%),乙酸(3.1%),糠醛(3.1%)等;苯甲醇、苯乙醇、茄酮、新植二烯等成分释放量与卷烟烟气较为接近;(3)不同种类HTPs气溶胶主要成分基本一致,但含氧裂解产物和酚类物质的释放量差别较大。
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关 键 词: | 加热烟草制品 气溶胶 主成分分析 多维气相色谱-质谱 |
收稿时间: | 2019-06-05 |
Composition analysis of heated tobacco products (HTPs) aerosol by MDGC/MS |
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Affiliation: | 1.Shanghai Tobacco Group Co., Ltd., Shanghai 200082, China2.Shanghai New Tobacco Product Research Institute, Shanghai 200082, China |
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Abstract: | In order to investigate the chemical composition of heated tobacco products (HTPs) aerosol, a total of 90 chemical compositions such as phenols, organic nitrogen compounds, oxygenated pyrolysis products, acids and alkenes from 17 typical HTPs were analyzed by heart-cutting two-dimensional gas chromatography-mass spectrometry. Results showed that: (1) The main component of HTPs aerosol is close to that of ordinary cigarette smoke, but the release amount is significantly lower, and the release amount per puff of 66.7% of the component types in HTPs aerosols less than 10% of the ordinary cigarette release amount; (2) The components with higher proportions of HTPs aerosol are glycerin (35.8%), nicotine (25.7%), 1, 2-propanediol (10.8%), acetic acid (3.1%), furfural (3.1%); the release amount of benzyl alcohol, phenethyl alcohol, solanone, and neophytadiene is close to that of cigarette smoke; (3) The main components in Different types of HTPs aerosols are basically the same, but the release amounts of oxygenated pyrolysis products and phenolic materials are quite different. |
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