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Isothermalin situ reduction kinetic analysis of NiCl2-containing gel
Authors:G C Das  A Basumallick  Kinjalkini Biswas  S Mukherjee
Affiliation:(1) Department of Metallurgical Engineering, Jadavpur University, 700 032 Calcutta, India;(2) Department of Metallurgical Engineering, Bengal Engineering College, 711 103 Howrah, India
Abstract:Isothermalin situ reduction kinetic study of NiCl2-containing gel was carried out. The detailed statistical as well as reduced time analysis show that contracting geometry and nucleation and growth type of mixed mechanisms are operative. The activation energy for reduction is in the range 158–193 kJ/mol. Thermal analysis on NiCl2-containing gel was carried out in the temperature range 800°C to 900°C.
Keywords:In situ reduction  isothermal kinetics  nanocomposites  sol-gel
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