| 香兰素对甲苯胺西夫碱及其轻,重络合物的Raman光谱研究 |
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| 引用本文： | 杨兆崎,刘国发.香兰素对甲苯胺西夫碱及其轻,重络合物的Raman光谱研究[J].哈尔滨建筑大学学报,1996,29(1):81-86. |
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| 作者姓名： | 杨兆崎 刘国发 |
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| 作者单位： | 东北电力学院，吉林大学，哈尔滨建筑大学 |
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| 摘 要： | 本文用独特的实验方法得到西夫碱稀土络合物的表面增强喇曼光谱（ＳＥＲＳ）、表面增强共振喇曼光谱（ＳＥＲＲＳ）。通过对样品的常规喇曼光谱的分析．指认了Ｌｎ－Ｃｌ、Ｌｎ－Ｎ、 Ｌｎ－Ｕ等键的伸缩振动谱带及Ｌｎ－（ＯＨ２）的面外摇摆振动谱带。讨论了西夫碱与它的不同原子序数的稀土元素的络合物光谱之间的差异
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| 关 键 词： | 席夫碱 稀土金属络合物 散射谱 光化学 香兰素 |
Study of Raman Spectra on Schiff Base and Its Light-weighty Rare Earth Complexes |
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| Yang Zhaoqi,Liu Guofa,Du Chun.Study of Raman Spectra on Schiff Base and Its Light-weighty Rare Earth Complexes[J].Journal of Harbin University of Civil Engineering and Architecture,1996,29(1):81-86. |
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| Authors: | Yang Zhaoqi Liu Guofa Du Chun |
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| Affiliation: | Yang Zhaoqi;Liu Guofa;Du Chun |
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| Abstract: | In this paper, Raman, SERS(Surface Enhanced Raman Scatrering)and SERRS(Suface Enhanced Resonance Raman Scattering) of Schiff base and its rare earth complexes are reported. The Raman bands difference between schiff base and itS rare earth complexes is dissussed. Then SERS and SERRS of Schiff base and its complexes absorbed on several metals are obtained. As a result, the vibra tion bands of Ln-O, Ln-N etc. are indicated and the differences of SERRS bands are ahalyzed. |
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| Keywords: | photochemistry schiff base raman spectrometry |
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