Abstract: | The feasibility and industrial potential of using bio‐flours from tropical crop residues, in particular starch containing bio‐flours, for the manufacture of bio‐composites was investigated. Polypropylene (PP) and poly(butylene succinate) (PBS) were compounded with bio‐flours from pineapple skin (P) and from non‐destarched (CS) and destarched (C) cassava root by twin‐screw extrusion. In CS composites, two levels of starch granules melting were achieved by adjusting the extrusion temperature, enabling control of morphological and mechanical properties. The use of bio‐flours reduced tensile strength by 26–48% and impact strength by 14–40% when the proportion of bio‐flour was increased to 40% w/w, while flexural strength initially increased upon addition of bio‐flours, before decreasing at higher loads. The use of compatibilizers, in particular maleic anhydride‐polypropylene (MAPP) in PP composites with 30% bio‐flour resulted in tensile strength similar to non‐compatibilized composites with 10% bio‐flour (34–35 MPa). MAPP also increased flexural strength to higher levels than pure PP, resulting in a stronger, but less flexible material. |