| 甲酸甲酯与乙烯加氢酯化合成丙酸甲酯 |
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| 引用本文： | 张勇 吴玉塘. 甲酸甲酯与乙烯加氢酯化合成丙酸甲酯[J]. 天然气化工, 1996, 21(1): 5-8 |
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| 作者姓名： | 张勇 吴玉塘 |
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| 作者单位： | 中国科学院成都有机化学研究所!610041 |
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| 摘 要： | 采用钌-碘催化体系,由甲酸甲酯和乙烯加氢酯化合成丙酸甲酯,同时还得到了高附加值的副产物3-戊酮和乙酸甲酯.考察了催化剂组成、溶剂以及反应温度、反应时间、乙烯始压等反应条件对反应的影响.
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| 关 键 词： | 甲酸甲酯 乙烯 加氢酯化 丙酸甲酯 钌 |
Preparation of methyl propionate from ethylene and methyl formate by hydroesterification |
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| Zhang Yong Wu Yutang Jia Zhaoxia. Preparation of methyl propionate from ethylene and methyl formate by hydroesterification[J]. Natural Gas Chemical Industry, 1996, 21(1): 5-8 |
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| Authors: | Zhang Yong Wu Yutang Jia Zhaoxia |
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| Abstract: | Methyl formate (MF) was used for ethylene hydroesterification to methyl propionate (MP) by using ruthenium-iodides as catalyst system. In the meantime, the valuable diethyl ketone (DEK) and methyl acetate (MA) were obtained as by-products. The influences of various parameters such as catalyst compositions, solvents, reaction temperature and time, initial pressure of ethylene on the reaction were investigated. |
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| Keywords: | : methyl formate ethylene hydroesterification methyl propionate ruthenium |
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