Regeneration of Pd/TiO2 catalyst deactivated in reductive CCl4 transformations by the treatment with supercritical CO2, ozone in supercritical CO2 or oxygen plasma |
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| Authors: | Ekaterina S. Lokteva Aleksey E. LazhkoElena V. Golubina Vadim V. TimofeevAlexander V. Naumkin Tatiana V. YagodovskayaSergey N. Gaidamaka Valery V. Lunin |
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| Affiliation: | a Chemistry Department of M.V.Lomonosov Moscow State University, Lengory 1, stroenie 3, 119991 Moscow, Russia
b A.N.Nesmeyanov Institute of Organoelement Compounds of RAS, Vavilova str. 28, 119991 Moscow, Russia |
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| Abstract: | Carbonaceous deposits formation was established as the primary reason of Pd/TiO2 catalyst deactivation during reductive processing of CCl4 to form hydrodechlorination and oligomerization products. Three methods of carbonaceous deposits elimination were tested: (1) extraction by supercritical CO2, (2) oxidation by ozone in supercritical CO2, and (3) low-temperature glow-discharge oxygen plasma treatment. Synchronic thermal analysis confirms effective carbonaceous deposits removal during regeneration by ozone or low temperature glow-discharge oxygen plasma; by XPS deep oxidation of surface Pd after oxidative treatment (by ozone or oxygen plasma) was found. Thus H2 reduction was proposed as the second step making possible full regeneration of initial catalytic activity of Pd/TiO2. |
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| Keywords: | Heterogeneous catalyst regeneration Deactivation Carbonaceous deposits Oxygen plasma Supercritical CO2 Ozone |
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