| 新型固体酸催化丁醇和环氧乙烷醚化 |
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| 引用本文： | 毛连山,朱凯,朱新宝,刘准.新型固体酸催化丁醇和环氧乙烷醚化[J].化学工业与工程技术,2006,27(3):26-29. |
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| 作者姓名： | 毛连山 朱凯 朱新宝 刘准 |
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| 作者单位： | 1. 南京林业大学,化工学院,江苏,南京,210037;江苏怡达化工有限公司,醇醚研发中心,江苏,江阴,214441
2. 江苏怡达化工有限公司,醇醚研发中心,江苏,江阴,214441 |
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| 摘 要： | 研究了丁醇和环氧乙烷在一种新型固体酸催化剂上的醚化反应。结果表明,这种新型固体酸具有很高的催化活性和较窄的相对分子质量分布。采用间歇釜式外循环反应器,在n丁醇∶n环氧乙烷=4∶1(物质的量比)、催化剂的质量为丁醇质量的0.4%、反应温度120℃、操作压力0.2~0.3 MPa的条件下,环氧乙烷的转化率为100%、乙二醇单丁醚的选择性较好。确定了最佳工艺参数并成功地进行了工业放大。
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| 关 键 词： | 固体酸催化剂 丁醇 环氧乙烷 乙二醇单丁醚 醚化反应 |
| 文章编号： | 1006-7906（2006）03-0026-04 |
| 收稿时间： | 2005-12-29 |
| 修稿时间： | 2005年12月29 |
Etherification of butanol with ethylene oxide by a new style solid acid catalyst |
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| Mao Lianshan,Zhu Kai,Zhu Xinbao,Liu Zhun.Etherification of butanol with ethylene oxide by a new style solid acid catalyst[J].Journal of Chemical Industry & Engineering,2006,27(3):26-29. |
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| Authors: | Mao Lianshan Zhu Kai Zhu Xinbao Liu Zhun |
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| Abstract: | Etherification of butanol with ethylene oxide by a new style solide acid catalyst is investigated.The results show that the new style catalyst possesses higher catalytic activity and narrow product distribution.Suitable reaction conditions in a batch reactor with circulator are as follows: the molar ratio of butanol to ethylene oxide is 4∶1,the mass fraction of the catalyst is 0.4% of butanol,the reaction temperature is 120℃,and the operational pressure is 0.2~0.3MPa.Under these conditions,the conversion of ethylene oxide is 100%.The best parameters are obtained and succeeded in carrying on industrialization. |
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| Keywords: | Solid acid catalyst Butanol Ethylene oxide Ethylene glycol monobutyl ether Etherification |
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