| 有机中间体合成中的新反应和新技术 |
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| 引用本文： | 张淑芬,杨锦宗. 有机中间体合成中的新反应和新技术[J]. 精细化工中间体, 1999, 0(5) |
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| 作者姓名： | 张淑芬 杨锦宗 |
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| 作者单位： | 大连理工大学!116012 |
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| 摘 要： | 详细介绍了蒽醌 １ 磺酸、卤化烷氧基钯酞菁、金属酞菁卤化物、卤代烷烃的新制备工艺， 在新型催化剂存在下饱和烃氧化成酮的新反应， 吡啶衍生物的卤化、硝基甲苯氧化成硝基苯甲酸、氧气液相氧化对硝基甲苯邻磺酸制备对硝基二苯乙烯双磺酸、固体酸催化山梨醇脱水成失水山梨醇的新技术。
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| 关 键 词： | 蒽醌1磺酸 卤化烷氧基钯酞菁 金属酞菁卤化物 卤代烷烃 硝基苯甲酸 对硝基二苯乙烯双磺酸 失水山梨醇 |
The New Reaction and New Technology in Synthesizing Organic Intermediates |
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| ZHANG Shufen YANG Jinzong. The New Reaction and New Technology in Synthesizing Organic Intermediates[J]. Fine Chemical Intermediates, 1999, 0(5) |
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| Authors: | ZHANG Shufen YANG Jinzong |
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| Affiliation: | Dalian University of Technology Dalian 116012 |
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| Abstract: | The new processes for producing anthraquinone 1 sulphonic acid, halogenated alkoxyphthalocyanine, high halogenated phthalocyanine and halogenated alkane were introduced in detail. The new oxidation reaction of alkane into ketong in the present of a fresh catalyst and the new technologies of the halogenation of pyridine derivative, oxidation of nitro toluene into nitro phenylformic acid, liquid oxidation of p nitro toluene o sulfonic acid into 4,4 dinitrostilbene 2,2 disulfonic acid and dehydration of sorbierite into dehydrated one were aslo shown. |
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| Keywords: | anthraquinone 1 sulphonic acid halogenated alkoxyphthalocyanine high halogenated phthalocyanine halogenated alkane nitro phenylformic acid 4 4 dinitrostilbene 2 2 disulfonic acid dehydrated sorbierite |
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