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Effect of Ti and Zr elements with equal mass ratio on microstructure and corrosion resistance of Zn-11Al-3Mg alloy
Authors:Mingming Zhang  Guorong Zhou  Huijie Sun  Xinying Teng  Zhenlu Zhao
Affiliation:School of Materials Science and Engineering, University of Jinan, Jinan, China
Abstract:In this study, the effect of Ti and Zr elements with equal mass ratio on microstructure and corrosion resistance of Zn-11Al-3Mg alloy was investigated. The microstructure was significantly refined and Al-rich phase transformed from dendrite to petal-like with the addition of Zr and Ti elements, due to the Al3(TixZr1 − x) phase as the nucleation substrate. The corrosion resistance of Zn-11Al-3Mg-x(Ti,Zr) alloy was effectively improved. Moreover, the corrosion products of Zn-Al-Mg alloy were not changed by the addition of Ti and Zr, which are mainly composed of Zn5(OH)8Cl2·H2O and Zn6Al2(OH)16CO3·4H2O.
Keywords:corrosion resistance  electrochemical properties  grain refinement  Zn-Al-Mg alloy
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