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Ruthenium‐Catalyzed Hydroamination of Aminoallenes: an Approach to Vinyl Substituted Heterocycles |
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| Authors: | Gianluigi Broggini Giovanni Poli Egle M. Beccalli Filippo Brusa Silvia Gazzola Julie Oble |
| Abstract: | Heterosubstituted aminoallenes underwent smooth ruthenium‐catalyzed intramolecular exo‐hydroamination reactions yielding the corresponding five‐, six‐, or seven‐membered 1,3‐diaza‐ or 1,3‐oxaza‐heterocyclic structures. This procedure is a valuable and less expensive alternative to the already known transition metal‐catalyzed hydroamination reactions of aminoallenes.  |
| Keywords: | allenes heterocycles homogeneous catalysis hydroamination ruthenium |