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Construction of FeS2‐Sensitized ZnO@ZnS Nanorod Arrays with Enhanced Optical and Photoresponse Performances
Authors:Mudan Wang  Chenxu Chen  Haiying Qin  Lei Zhang  Youtong Fang  Jiabin Liu  Liang Meng
Abstract:FeS2‐sensitized ZnO@ZnS nanorod arrays are fabricated by a two‐step solution immersion and a subsequent sulfurization. The material properties including structure, morphology, and photoluminescence are investigated by a variety of characterization methods. As compared with ZnO@ZnS core/shell structure, FeS2‐sensitized ZnO@ZnS nanorod arrays show improved optical absorption property with the extension of the absorption edge into the range of visible light. The photoresponse performance of FeS2‐sensitized Zno@ZnS is also enhanced as the photocurrent density at 1.0 V is dozens of times larger than that of ZnO@ZnS nanorods. The cause for the difference in such material properties of these two materials is discussed. In this work, a new method for sensitizing wide bandgap ZnO@ZnS nanorod arrays with improved light response performance is presented.
Keywords:FeS2‐sensitized ZnO@ZnS nanorods  heterostructures  optical absorption  photoresponse  ZnO@ZnS nanorods
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