Structure and photocatalytic property of a new Cu(II) based framework with jsm topology |
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| Affiliation: | 1. Department of Chemistry, Changchun Normal University, Changchun 130032, People''s Republic of China;2. Central Laboratory, Changchun Normal University, Changchun 130032, People''s Republic of China;1. Engineering Research Center of Photoelectric Functional Material, College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu 476000, PR China;2. School of business administration, Zhengzhou University of Aeronautics, Zhengzhou 450046, PR China |
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| Abstract: | A new coordination polymer [Cu(mip)(bpy)0.5]n (1) was obtained through reaction of 5-methylisophthalic acid (H2mip) and 4,4′-bipyridine (bpy) with copper nitrate under hydrothermal condition. X-ray single crystal diffraction analysis reveals that complex 1 exhibits a 3D network with jsm topology. Photocatalytic activity of the complex has also been characterized. Notably, complex 1 represents the rare example of visible-light-driven photocatalyst based on coordination polymer and shows good degradation ability over methylene blue (MB). |
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