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Fabrication of Bi2MoO6 nanoplates hybridized with g-C3N4 nanosheets as highly efficient visible light responsive heterojunction photocatalysts for Rhodamine B degradation
Affiliation:1. Department of Chemistry, School of Sciences, Zhejiang Sci-Tech University, 928 Second Avenue, Xiasha Higher Education Zone, Hangzhou, China;2. Center for Composite Material, Harbin Institute of Technology, Harbin, China;3. College of Materials Science and Engineering, China Jiliang University, Hangzhou, China
Abstract:The Bi2MoO6/g-C3N4 heterojunction photocatalysts have been successfully fabricated using a simple liquid chemisorptions and thermal post-treatment. These nanostructured Bi2MoO6/g-C3N4 composites were extensively characterized by X-ray diffraction(XRD), field emission scanning electron microscopy (FESEM), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR),UV–vis diffuse reflectance spectra (UV–vis DRS) and Photoluminescence (PL). The photocatalytic results show that 20 wt% Bi2MoO6/g-C3N4 sample exhibits efficient visible light activity and excellent photo-stability. The kinetic constant of RhB degradation over 20 wt% Bi2MoO6/g-C3N4 is about 5 and 2.5 times higher than that over pure Bi2MoO6 and g-C3N4 nanosheets, respectively. The enhanced photocatalytic performance is attributed to the construction of heterogeneous interface to promote photo-induced charge carrier pairs separation.
Keywords:Heterojunction photocatalyst  Visible light
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