Syntheses,structures and photocatalytic properties of two coordination polymers based on bis(1,2,4-triazol-4-ylmethyl)benzene and multicarboxylates |
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| Affiliation: | 1. Shaanxi Key Laboratory of Comprehensive Utilization of Tailings Resources, College of Chemical Engineeringand Modern Materials, Shangluo University, Shangluo 726000, China;2. School of Chemistry and Environmental Engineering, Sichuan University of Science & Engineering, Zigong, PR China;3. Department of Chemistry, Faculty of Science, University of Lucknow, Lucknow 226 007,India;1. Department of Chemistry, Tianjin University, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, PR China;2. Tianjin Entry-Exit Inspection and Quarantine Bureau, Tianjin 300457, PR China;3. Laboratory of Inorganic Synthesis and Catalysis, Institute of Chemical Sciences and Engineering, Ecole Polytecnique Fédérale de Lausanne (EPFL), ISIC-LSCI, BCH 3218, Lausanne 1015, Switzerland |
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| Abstract: | Two coordination polymers {Cu4(OH)2(btrb)2(btc)2]·4H2O}n (1) and {Cd2(btrb)(adc)2(H2O)]·H2O}n (2) were synthesized with hydrothermal method and characterized (btrb = 1,4-bis(1,2,4-triazol-4-ylmethyl)benzene, btc = 1,3,5-benzenetricarboxylate, adc = 1,3-adamantanedicarboxylate). 1 shows an unusual (3,10)-connected two-dimensional metal–organic framework based on the tetranuclear copper(II) cluster Cu4(μ3-OH)2]. 2 is an interesting three-dimensional network based on the one-dimensional metal–organic nanotube. 1 shows good photocatalytic activity for the degradation of methyl blue (MB). The luminescence of 2 was investigated. |
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