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The effects of vacuum annealing on the structure of VO2 thin films
Authors:Y.L. Wang  M.C. Li  L.C. Zhao
Affiliation:Key Laboratory of Precision Hot-Forming for National Defense Science and Technology, School of Material Science and Engineering, Harbin Institute of Technology, P.O. Box 428, Harbin 150001, China
Abstract:Noncrystalline VOx thin films were deposited onto p-doped Si (100) substrates at 400 °C using magnetron sputtering. By vacuum annealing, we obtained polycrystalline VO2 thin films with two different structures under a variety of annealing conditions. With the annealing temperature increasing and the annealing time developing, structures of the films underwent the following transformation: amorphous structure→metastable VO2 (B)→VO2 (B) + VO2 (M). Vacuum annealing is useful of acquiring VO2 thin films with high surface quality, but too high annealing temperature (500 °C) and too long time (15 h) are harmful, which make the surface degenerate.
Keywords:81.1577.Cd   36.20.Ng   81.40.Ef
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