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Propane partial oxidation to acrolein over combined catalysts
Authors:M.Yu. Sinev  O.V. Udalova  Y.P. Tulenin  L.Ya. Margolis  V.P. Vislovskii  R.X. Valenzuela  V. Cortés Corberán
Affiliation:(1) Semenov Institute of Chemical Physics, RAS, 4 Kosygin street, 117334 Moscow, Russia;(2) Institute of Inorganic and Physical Chemistry, Azerbaijan Academy of Sciences, 29 H. Javid avenue, 370143 Baku, Azerbaijan;(3) Instituto de Catálisis y Petroleoquímica, CSIC, Campus UAM Cantoblanco, 28049 Madrid, Spain
Abstract:A novel approach for the partial oxidation of propane to acrolein, based on the use of layers of combined catalysts in a single reactor, provides good yields of acrolein with selectivity above 62%. The results depend strongly on the layer configuration, and reveal new mechanistic features for the process. This revised version was published online in August 2006 with corrections to the Cover Date.
Keywords:propane partial oxidation  acrolein production from propane  combined catalysts  heterogeneous–  homogeneous processes  selective oxidation of alkanes
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