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Poly(methacrylate)‐derived diblock dispersant for TiO2 in aqueous suspensions
Authors:Chia‐Chen Li  Shinn‐Jen Chang  Chi‐Wei Wu  Cha‐Wen Chang
Affiliation:1. Institute of Materials Science and Engineering, and Department of Materials & Mineral Resources Engineering, National Taipei University of Technology, Taipei, Taiwan;2. Material and Chemical Research Laboratories, Industrial Technology Research Institute, Hsinchu, Taiwan
Abstract:In this paper, we propose a newly designed dispersant, ammonium poly(methacrylate)‐block‐poly(2‐phenoxyethyl acrylate) (PMA‐b‐PBEA), and our rheological and zeta potential test results verify its superior dispersion efficiency for aqueous suspensions in comparison to the commercial dispersant ammonium polyacrylate (PAA‐NH4). The extremely high dispersion efficiency of PMA‐b‐PBEA correlates closely to its diblock structure, which simultaneously exhibits a less polar anchoring head group and a water‐dissociable stabilizing moiety. The unique structure of PMA‐b‐PBEA accounts for its high powder adsorption effectiveness, which is demonstrated in its adsorption capability being double that of PAA‐NH4.
Keywords:dispersants/dispersion  processing  suspensions  tape casting  titanium oxide
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