Surface plasmon characteristics of nanocrystalline gold/DLC composite films prepared by plasma CVD technique |
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Authors: | R Paul S Hussain S Majumder S Varma AK Pal |
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Affiliation: | aDepartment of Instrumentation Science, USIC Building, Jadavpur University, Calcutta 700 032, India;bInstitute of Physics, Bhubaneswar, India |
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Abstract: | Composite films containing gold nanoparticles embedded in diamond-like carbon (Au–DLC) matrix were deposited on glass and Si (1 0 0) substrates by using capacitatively coupled plasma (CCP) chemical vapour deposition technique (CVD). Particle size and metal volume fraction varied between 2.7–3.5 nm and 0.04–0.7, respectively with the amount of argon in the methane + argon gas mixture in the plasma. Bonding environment in these films were obtained from XPS, Raman and FTIR studies. Microstructural studies were carried out by SEM, XRD and TEM studies. Blue-shift of the surface plasmon resonance peak (located 540–561 nm) in the optical absorbance spectra of the films could be associated with the reduction of the particle size while red shift was associated with the increase in volume fraction of metal particles. The experimental results have been discussed in light of the core–shell model. |
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Keywords: | Surface plasmon Diamond-like carbon Nanocrystalline gold |
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