| Kyodai硝化法合成1-硝基金刚烷 |
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| 引用本文： | 张琳,马伟,罗军.Kyodai硝化法合成1-硝基金刚烷[J].精细化工中间体,2009,39(6):22-24,39. |
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| 作者姓名： | 张琳 马伟 罗军 |
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| 作者单位： | 南京理工大学化工学院,江苏,南京,210094 |
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| 摘 要： | 将二氧化氮-臭氧体系用于金刚烷的直接硝化合成重要中间体1-硝基金刚烷，研究二氧化氮用量、反应时间、反应温度和臭氧流量等因素对反应的影响，在n（金刚烷）：n（二氧化氮）=1：15、臭氧流量为0．4L／min、-30℃下反应2h的优化条件下，金刚烷的转化率为99．9％，1-硝基金刚烷的收率为90．9％，当n（金刚烷）：n（二氧化氮）=1：30时，1-硝基金刚烷的收率可达92．1％。
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| 关 键 词： | 1-硝基金刚烷 金刚烷 Kyodai硝化 绿色化学工艺 |
Synthesis of 1-Nitroadamantane via Kyodai Nitration |
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| ZHANG Lin,MA Wei,LUO Jun.Synthesis of 1-Nitroadamantane via Kyodai Nitration[J].Fine Chemical Intermediates,2009,39(6):22-24,39. |
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| Authors: | ZHANG Lin MA Wei LUO Jun |
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| Affiliation: | (School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 21009, China) |
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| Abstract: | 1 -Nitroadamantane was synthesized from adamantine by direct nitration with NO2-O3. The reaction afforded 1-nitroadamantane in 90.9% yield with adamantine conversion of 99.9% under the optimized conditions: n (adamantine) ∶ n (NO2) = 1 ∶ 15, flow rate of O3 = 0.4 L / min, reaction temperature -30℃, reaction time 2 h. Moreover, when 30 equivalents of NO2 was used, 1-nitroadamtane was obtained in a higher yield of 92.1%. This technology avoids use of nitrous acid, and therefore is a green process. |
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| Keywords: | 1-nitroadamantane adamantine Kyodai nitration green chemical process |
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