| 三模板剂法合成钛硅介孔纳米球 |
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| 引用本文： | 黄永茂,徐智策,张志艳,张雪梅.三模板剂法合成钛硅介孔纳米球[J].河北机电学院学报,2010(1):26-28. |
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| 作者姓名： | 黄永茂 徐智策 张志艳 张雪梅 |
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| 作者单位： | [1]河北化工医药职业技术学院化学与环境工程系,河北石家庄050026 [2]河北科技大学化学与制药工程学院,河北石家庄050018 |
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| 摘 要： | 以十二烷基硫酸钠（DDS）、十六烷基三甲基溴化铵（CTAB）、聚丙烯-聚乙烯-聚丙烯三嵌段共聚物（P123）为模板剂，以硫酸钛和偏硅酸钠为金属源，使用三模板剂法首次合成出钛硅介孔纳米球材料。用XRD，ICP，HRTEM，SEM，FTIR和低温氮吸附等多种手段对材料进行了袁征。结果表明，所制备的钛-硅材料是介孔纳米球结构，球径约为2000nm。当n（钛）／n（硅）增加时，介孔孔径增大，比表面积降低。
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| 关 键 词： | 三模板剂 钛-硅 介孔 纳米球 |
Synthesis of mesoporous titanium-silica nanosphere using tri-surfactant method |
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| Authors: | HUANG Yong-mao XU Zhi-ce ZHANG Zhi-yan ZHANG Xue-mei |
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| Affiliation: | 1. Department of Chemical and Environmental Engineering, Hebei Chemical and Pharmaceutical College, Shijiazhuang Hebei 050026, China; 2. College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang Hebei 050018,China) |
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| Abstract: | Mesoporous titanium-silica nanosphere was synthesized by tri-surfactant method, using dodecyl sodium sulfate （DDS）, Cetyltrimethylammonium bromide （ CTAB）, Poly （ propylene glycol）-block- poly （ ethylene glycol）- poly （ propylene glycol） （P123） as surfactant and titanium sulfate,sodium silicate as metal source. The material was characterized by XRD,nitrogen adsorption/desorption, ICP, HRTEM, SEM and FTIR. The results indicate that the synthesized sample is mesoporous nanosphere material,diameter of the sphere is about 2 000 nm. When the molar ratio of titanium/silica increases, pore size increases and surface area decreases. |
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| Keywords: | tri-surfactant titanium-silica mesoporous nanosphere |
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