Abstract: | The electrical conductivity and thermoelectric power of Mn-doped BaTiO3 (1 mole%) and undoped BaTiO3 have been measured as functions of oxygen partial pressure (in the range of 10-16 to 1 atm) and temperatures (in the range of 900 to 1200°C), and compared with each other to differentiate the effect of the Mn-addition. It is found that the isothermal conductivity of Mn-doped BaTiO3 varies with increasing Po2 as
to
to
, unlike previously reported. This behavior is well explained by the shift of the ionization equilibrium,
. The corresponding equilibrium constant, KA, is determined from the Po2 values demarcating those three different Po2 regions as
=3.19×1022 exp(–1.69 eV/kT). Basic parameters involving carrier density and mobility, and defect structure of Mn-doped BaTiO3 are discussed in comparison with those of undoped BaTiO3. |