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低碳烷烃催化脱氢与逆水煤气变换偶合转化的研究进展
引用本文:章治平.低碳烷烃催化脱氢与逆水煤气变换偶合转化的研究进展[J].化学工程师,2005,19(3):27-29.
作者姓名:章治平
作者单位:石油化工科学研究院,北京,100083
摘    要:本文综述了近年来国内外有关利用CO2为氧化剂经由逆水煤气变换与低碳烷烃脱氢进行偶合转化反应的研究状况。对几种CO2选择氧化低碳烷烃的反应研究进行了归纳总结。分析讨论了低碳烷烃催化反应与CO2偶合转化的作用机制,并提出了研究展望。

关 键 词:低碳烷烃  逆水煤气变换  脱氢  芳构化  偶合转化
文章编号:1002-1124(2005)03-0027-04
修稿时间:2005年1月6日

Development of research on the coupled catalytic conversion of light alkanes and carbon dioxide
ZHANG Zhi-ping.Development of research on the coupled catalytic conversion of light alkanes and carbon dioxide[J].Chemical Engineer,2005,19(3):27-29.
Authors:ZHANG Zhi-ping
Abstract:Recent advances in the selective oxidation of alkanes by using CO_2 as the oxidant were reviewed. The subjects included in this articles are the dehydrogenation of light alkanes to alkenes or further dehydrocyclodimerization to aromatics, the oxidative coupling of reverse-water gas reaction by introducing CO_2 in the presence of different kinds of catalysts. Discussion is focused on the role of CO_2 in the selective oxidative reactions and the related mechanisms.
Keywords:light alkanes  reverse-water gas reaction  oxidative dehydrogenation  aromatization  coupled catalytic conversion
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