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Sulfur dioxide adsorption by activated carbons having different textural and chemical properties
Authors:Nilgün Karatepe  İlkün Orbak  Reha Yavuz  Ayşe Özyuğuran
Affiliation:1. Istanbul Technical University, Institute of Energy, Renewable Energy Division, 34469 Maslak, Istanbul, Turkey;2. Istanbul Technical University, Chemical and Metallurgical Engineering Faculty, 34469 Maslak, Istanbul, Turkey
Abstract:Activated carbons from Turkish lignite were prepared with different methods to investigate the influence of physico-chemical characteristics of the carbon materials on the sulfur dioxide (SO2) adsorption. The effects of SO2 concentration, adsorption temperature, and sample particle size on adsorption were investigated using a thermogravimetric analysis system. An intraparticle diffusion model based on Knudsen diffusion and Freundlich isotherm (or Henry isotherm) was applied for predicting the amount of SO2 adsorbed. The textural and chemical properties of the activated carbon samples, resulted from the effects of activation conditions and demineralization of the carbon precursor, on the SO2 adsorption were also analyzed.
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