Magnetic Properties of FePt Nanoparticles Prepared by a Micellar Method |
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Authors: | Y Gao X W Zhang Z G Yin S Qu J B You and N F Chen |
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Affiliation: | (1) Key Lab of Semiconductor Materials Science, Institute of Semiconductors, CAS, Beijing, 100083, People’s Republic of China; |
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Abstract: | FePt nanoparticles with average size of 9 nm were synthesized using a diblock polymer micellar method combined with plasma
treatment. To prevent from oxidation under ambient conditions, immediately after plasma treatment, the FePt nanoparticle arrays
were in situ transferred into the film-growth chamber where they were covered by an SiO2 overlayer. A nearly complete transformation of L10 FePt was achieved for samples annealed at temperatures above 700 °C. The well control on the FePt stoichiometry and avoidance
from surface oxidation largely enhanced the coercivity, and a value as high as 10 kOe was obtained in this study. An evaluation
of magnetic interactions was made using the so-called isothermal remanence (IRM) and dc-demagnetization (DCD) remanence curves
and Kelly–Henkel plots (ΔM measurement). The ΔM measurement reveals that the resultant FePt nanoparticles exhibit a rather weak interparticle dipolar coupling, and the absence
of interparticle exchange interaction suggests no significant particle agglomeration occurred during the post-annealing. Additionally,
a slight parallel magnetic anisotropy was also observed. The results indicate the micellar method has a high potential in
preparing FePt nanoparticle arrays used for ultrahigh density recording media. |
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Keywords: | FePt nanoparticles Reverse micelles Self-assembly Interparticle exchange coupling Magnetic recording |
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