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Conductivity of (NH_4)_3[CrMo_6O_(24)H_6]·7H_2O Treated by Nd Chemistry-Heated Diffused Permeation
作者姓名:Xin LI Zhonghua LI  Yuzhi GAO Maomao ZHAO  Yuanru GUO and Baibin ZHOU
作者单位:Xin LI1) Zhonghua LI1),Yuzhi GAO1) Maomao ZHAO1),Yuanru GUO1) and Baibin ZHOU2)1) Department of Applied Chemistry,Harbin Institute of Technology,Harbin 150001,China2) Department of Chemistry,Harbin Normal University,Harbin 150080,China
摘    要:1.IntroductionDue to special constructions,POMs(polyoxometa-lates)have received much attention recently in materialchemistry1~3].However,the property of conductivity re-duces with increasing temperature4~6],which limits itsapplication greatly.In this paper,rare earth co-permeation5]was usedto treat(NH4)3CrMo6O24H6]·7H2O with Nd.The com-position was determined by chemical analysis,TG-DTA,XRF and XRD.The XRD results indicate that the com-pound has Anderson structure.The product,…

关 键 词:Rare  earths  (NH_4)_3[CrMo_6O_(24)H_6]·7H_2O  Chemistry-heated  diffused  permeation  Conductivity
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