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Measurement of Small Concentrations of Chromium and Iron in Rutile (TiO2) Using Electron Spin Resonance
Authors:Ronaldo S. de  Biasi   Antonio A. R. Fernandes  Maria L. N. Grillo
Affiliation:Seção de Engenharia Mecãnica e de Materiais, Instituto Militar de Engenharia, 22290 Rio de Janeiro, RJ, Brazil
Abstract:Electron spin resonance linewidths of Cr3+ and Fe3+ in rutile were measured in samples doped with Cr and Fe. The linewidth was found to change in a predictable way with Cr and Fe concentration. The experimental results show that the technique can be used to measure, rapidly and nondestructively, small concentrations of Cr and Fe in commercial TiO2.
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