| 丙烯腈光聚合研究 |
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| 引用本文： | 贺继东,王娟.丙烯腈光聚合研究[J].化学推进剂与高分子材料,2005,3(6):45-47. |
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| 作者姓名： | 贺继东 王娟 |
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| 作者单位： | 1. 青岛科技大学高分子科学与工程学院,山东,青岛,266042
2. 青岛大学医学院化学系,山东,青岛,266021 |
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| 摘 要： | 研究偶氮二异丁腈(AIBN)作光引发剂引发丙烯腈(AN)的光聚合,探讨了单体浓度、引发剂浓度、光照时间和环境温度对单体转化率、聚合物黏均相对分子质量的影响。总结出光引发剂C60-(SR)n(C60负载引发-转移-终止剂)与常规光引发剂AIBN引发AN光聚合的区别。
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| 关 键 词： | 丙烯腈 光聚合 光引发剂 |
| 文章编号： | 1672-2191(2005)06-0045-03 |
| 修稿时间： | 2005年8月5日 |
Photopolymerization of Acrylonitrile |
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| HE Ji-dong,WANG Juan.Photopolymerization of Acrylonitrile[J].Chemical Propellants & Polymeric Materials,2005,3(6):45-47. |
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| Authors: | HE Ji-dong WANG Juan |
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| Affiliation: | HE Ji-dong1,WANG Juan2 |
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| Abstract: | The photopolymerization of acrylonitrile initiated by AIBN was studied. The influence of monomer concentration, photoinitiator concentration, illumination time and environmental temperature on the acrylonitrile conversion and the polymer viscosity average relative molecular mass is discussed. The differences of photopolymerization systems are summarized, in which C60-(SR)n (iniferter supported with C60 ) and AIBN are respectively used as photoinitiator. |
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| Keywords: | acrylonitrile photopolymerization photoinitiator |
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